Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS     

Yu Liu  Qiu‐Li Li  Guo‐Qiang Tang  Xian‐Hua Li 《Geostandards and Geoanalytical Research》2020,44(3):421-437

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.  相似文献   

西准噶尔红山地区晚古生代赞岐岩锆石U Pb年代学、地球化学特征及其地质意义   总被引：1，自引：0，他引：1  

马飞宙  陈宣华  徐盛林  马芬  韩乐乐  丁伟翠  王叶 《地质学报》2020,94(5):1462-1481

中亚造山带西部西准噶尔地区红山花岗岩体内部发育多期似岩墙状安山质暗色条带,LA-ICP-MS锆石U-Pb同位素定年和岩石化学与同位素分析表明,它们具有不同的形成年龄、相同的源区和相似的形成过程。其中,具有不规则状或环状形态的暗色条带,其锆石U-Pb年龄为319.1±2.9 Ma和313.3±2.4 Ma,远大于红山岩体花岗岩锆石结晶年龄(305～301Ma),可能是红山岩体侵位过程中所捕掳的围岩;具有线性展布特征的安山质暗色条带,其锆石U-Pb年龄为295±2Ma,形成于红山岩体侵位之后,构成伸展岩墙群。红山岩体中的安山质暗色条带和线状岩墙群具有相似的岩石化学组成,富SiO_2(56.48%～63.09%)、MgO(3.56%～6.31%),具有高的Mg#值(51.74～62.40)及Na_2O/K_2O值(1.34～3.43);球粒陨石标准化稀土元素(REE)配分模式呈明显的右倾型,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、K、Ba、U、Sr,亏损高场强元素(HFSE)Th、Nb、Ce、P和重稀土元素,具较弱的负铕异常;其同位素组成特征为(~(87 )Sr/~(86 )Sr)i=0.703295～0.703620,(~(143) Nd/~(144) Nd)i=0.512612～0.512618,εNd(t)=6.91～7.62,(~(206) Pb/~(204) Pb)t为17.6883～17.9876,(~(207) Pb/~(204) Pb)t为15.5313～15.5686,(~(208)Pb/~(204)Pb)t为37.4460～38.0581。它们具有与赞岐岩类似的地球化学特征,总体表现出与弧岩浆作用相关的地球化学特征,可能具有共同的物质来源,为准噶尔洋板片俯冲消减后同一地幔源区在不同阶段的产物。其中,形成于弧岩浆作用时期的赞岐岩(319～313 Ma),构成与岛弧花岗岩类伴生的环状似岩墙状安山质暗色条带;形成于后造山伸展岩浆作用晚期的赞岐岩(～295Ma),构成与达拉布特左行走滑作用相关的陆内伸展岩墙群。安山质暗色条带(岛弧火山作用)、红山岩体(后造山伸展)和线状岩墙群(陆内伸展)记录了西准噶尔红山地区洋陆转换的全过程。  相似文献   

陕西黑河流域地下水水化学特征     

王晓艳 《中国沙漠》2019,39(4):168-176

2017年在秦岭黑河流域7个采样点进行地下水样品采集。通过综合分析、Gibbs图、Piper三角图、主要离子比值法、主成分分析法得出黑河地下水化学成分的特点、水化学类型及其成因。结果表明：阳离子的主要组成成分是Ca²⁺，HCO₃^-是阴离子的主要组成成分，黑河流域地下水化学类型为HCO₃^-- Ca²⁺和SO₄^2--HCO₃^--Ca²⁺型。Gibbs图分析得出该地下水化学离子组成受岩石风化作用控制；Piper三角图、主要离子比值法、主成分分析及相关分析表明，地下水化学组分主要受方解石、白云岩等碳酸盐岩矿物的风化溶解，同时伴有硫酸溶解碳酸盐岩，受硅酸盐岩的溶解控制作用较小。  相似文献   

东北三省城市土地利用效益评价及耦合协调关系研究   总被引：3，自引：1，他引：2  

田俊峰  王彬燕  王士君 《地理科学》2019,39(2):305-315

在阐述城市土地利用效益系统耦合协调性内涵及其交互作用机理的基础上,构建综合评价指标体系,运用均方差决策法、耦合协调度模型,对东北三省2003~2015年城市土地利用综合效益及其主成分间耦合协调关系进行测度,并分析其时空演化过程。研究认为：① 城市土地利用综合效益表现出随时间“先升后降”的特征,区内三省间差异明显,中心和门户城市长期处于较高水平。② 城市土地利用经济效益亦存在“先升后降”的时序变化特征,空间上表现为“南高北低”,低值区范围缩减明显;社会效益差异不显著,在南北方向上表现出“凸”字型分布特征;区域生态环境效益整体较高,高值区由集中趋向分散。③ 城市土地利用经济、社会、生态环境效益间耦合协调关系在各时间节点均表现为失调,且以中度失调为主,但中心城市和门户城市的三效益耦合协调关系相对较好,向协调方向发展,哈长与辽中南城市群地区协调性优于其他区域,吉林省与辽宁省东部的部分城市协调关系趋向恶化。④ 城市土地利用效益间关系失调主要受复合因素的作用,经济效益滞后是制约土地利用效益耦合协调关系提升的主因,生态环境效益滞后不是限制土地利用效益耦合协调性提升的主要因素。  相似文献   

Estimation of Grassland Production in Central and Eastern Mongolia from 2006 to 2015 via Remote Sensing     

LI Ge  WANG Juanle  WANG Yanjie  WEI Haishuo 《资源与生态学报(英文版)》2019,10(6):676-684

Mongolia is an important part of the Belt and Road Initiative “China-Mongolia-Russia Economic Corridor” and a region that has been severely affected by global climate change. Changes in grassland production have had a profound impact on the sustainable development of the region. Our study explored an optimal model for estimating grassland production in Mongolia and discovered its temporal and spatial distributions. Three estimation models were established using a statistical analysis method based on EVI, MSAVI, NDVI, and PsnNet from Moderate Resolution Imaging Spectroradiometer (MODIS) remote sensing data and measured data. A model evaluation and accuracy comparison showed that an exponential model based on MSAVI was the best simulation (model accuracy 78%). This was selected to estimate the grassland production in central and eastern Mongolia from 2006 to 2015. The results show that the grassland production in the study area had a significantly fluctuating trend for the decade study; a slight overall increasing trend was observed. For the first five years, the grassland production decreased slowly, whereas in the latter five years, significant fluctuations were observed. The grassland production (per unit yield) gradually increased from the southwest to northeast. In most provinces of the study area, the production was above 1000 kg ha ^-1, with the largest production in Hentiy, at 3944.35 kg ha ^-1. The grassland production (total yield) varied greatly among the provinces, with Kent showing the highest production, 2341.76×10 ⁴ t. Results also indicate that the trend in grassland production along the China-Mongolia railway was generally consistent with that of the six provinces studied.  相似文献   

闽中南平—宁化构造带南华纪陆缘弧岩浆活动：对武夷造山带构造演化的新启示     

姜杨  赵希林  李龙明  潘桂棠  徐敏成  黄文成  刘欢 《中国地质》2020,47(4):1010-1024

南平—宁化构造带沿线出露着以万全岩群和楼前组、西溪组等为代表的一系列新元古代火山-沉积岩系。系统的岩石学、年代学和地球化学研究表明,福建明溪和江西瑞金地区的楼前组浅变质英安岩和晶屑凝灰岩分别形成于(729±4)Ma和(735±6.7)Ma(LA-ICP-MS锆石U-Pb法),SiO2含量变化在65.22%～74.54%,相对富Al2O3(11.05%～16.80%)富碱(Na2O+K2O=4.88%～10.19%)而贫CaO、MgO和FeOT,ANK值和A/CNK值分别为1.23～1.78和0.98～1.57,Nb/Ta=12.44～17.28,Nd/Th=2.07～3.51,Ti/Zr=6.08～10.37,Ti/Y=68.51～154.71,属过铝质S型火山岩;明显富集大离子亲石元素(Ba、Rb等)而亏损高场强元素(Nb、Ta、Ti、P等),Zr/Nb=16.65～24.07,Th/Ta=12.94～16.93,δEu呈现明显负异常(0.33～0.62),显示岛弧岩浆岩的地球化学特征。综合区域地质资料及前人研究结果提出,南平—宁化一线在713 Ma前为活动大陆边缘环境,洋壳俯冲引发的岩浆活动形成了沿南平—宁化—瑞金一线展布的陆缘弧中酸性火山岩带,暗示此时南、北武夷之间尚未拼合形成统一的武夷地块,因而华夏地块不存在统一的前南华纪结晶基底。  相似文献   

西藏甲玛铜多金属矿床磁黄铁矿标型矿物学特征及其地质意义   总被引：2，自引：0，他引：2  

杨阳  唐菊兴  吴纯能  林彬  唐攀  张泽斌  何亮  祁婧  李怡萱 《矿床地质》2020,39(2):337-350

甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%～60.71%,平均为60.38%,w(S)为38.18%～38.69%,平均38.35%,化学分子式为Fe_8S_9～Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%～59.57%,平均为59.10%,w(S)为39.28%～39.95%,平均39.59%,化学分子式为Fe_5S_6～Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献   

浅析广安华蓥山区山水林田湖综合治理措施——以高顶山矿区为例     

李飞  裴云婧  王维  李德星  张春茂 《四川地质学报》2020,40(1):80-85

高顶山矿区位于广安华蓥市城区东南约5km处。长期的采矿活动,导致区内矿山地质环境问题突出,严重影响华蓥山地区人民的生命财产安全。矿山地质环境问题亟待解决。本文通过分析区内主要存在的矿山地质环境问题,提出通过矿山地质灾害、矿山土地恢复、矿山地形地貌景观恢复治理,河道综合整治、道路修复、生态保育、产业提升等措施;消除安全隐患,保障区内人民生命财产安全;改善生态环境,实现华蓥山地区生态环境全面恢复,生态环境质量提升,提高环境承载力,实现区内"山青、水秀、林美、田良"的目标。并对区内的产业转型升级进行了探讨,提出将高顶山矿区建设成具有科普和教育价值的旅游景观目的地;利用矿区独具特色工业人文景观和别致的自然景观,将高顶山矿区建设成集"科普、休闲、康养、户外、探秘"五大功能于一体的矿山公园,推动矿业经济转型升级,促进产业结构转型和经济社会可持续发展。  相似文献   

西藏类乌齐地区含镍碳酸岩的发现与地质意义     

周新  冯德新  樊炳良  余佳树  嘎桑顿珠  易金龙 《矿物学报》2020,(2):109-115

野外调查发现西藏类乌齐地区分布着众多的含镍碳酸岩体,呈十几米至几百米不等的岩株出露。岩体与超基性岩之间具明显的港湾状、枝状侵入接触、岩石不具层理、岩石表现出细粒结晶等粒结构、岩体内见超基性岩捕掳体等特征均表明其为火成碳酸岩岩体。在成分上以菱镁矿为主,岩石中MgO的含量为27.16%~31.75%,为镁质碳酸岩。岩石稀土元素配分曲线呈平缓右倾的轻稀土富集型,轻重稀土元素分馏现象明显,具有明显的Eu正异常和弱的Ce负异常;微量元素显示Rb、Th、Nb、Hf元素相对富集,K、U、Ti元素相对亏损。含镍碳酸岩可能是富CO2的深部流体在中下地壳对超基性岩交代的结果,具备寻找硫化镍矿床的有利条件。  相似文献